Name | Erbium(III) nitrate pentahydrate |
Synonyms | ERBIUM NITRATE erbium trinitrate ERBIUM NITRATE, HYDROUS ERBIUM NITRATE PENTAHYDRATE ERBIUM (III) NITRATE HYDRATE ERBIUM(+3)NITRATE PENTAHYDRATE Erbium(III) nitrate pentahydrate erbium(+3) cation nitrate pentahydrate |
CAS | 10031-51-3 |
EINECS | 233-436-7 |
InChI | InChI=1/Er.NO3.5H2O/c;2-1(3)4;;;;;/h;;5*1H2/q+3;-1;;;; |
Molecular Formula | H10ErNO8 |
Molar Mass | 319.339 |
Melting Point | 130℃ -4H?O |
Water Solubility | Typically insoluble in water. |
Appearance | Crystals or Crystalline Powder |
Color | Pink |
Stability | Hygroscopic |
Sensitive | Hygroscopic |
Physical and Chemical Properties | Chemical formula Er(NO3)3 · 5H2O. Molecular weight 443.37. Light red crystal. Heat to 130 ℃ and lose 4 molecules of crystal water. Erbium oxide is generated by high temperature decomposition. Soluble in water, ethanol, ether, acetone. Vibration or heating can cause an explosion. |
Use | Scientific research reagents, biochemical research is used in intermediate compounds, glass, chemical reagents and other industries. |
Risk Codes | R8 - Contact with combustible material may cause fire R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes |
Safety Description | S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/39 - |
UN IDs | UN 1477 5.1/PG 2 |
WGK Germany | 3 |
TSCA | Yes |
HS Code | 28469000 |
Hazard Class | 5.1 |
Packing Group | III |
Downstream Products | Erbium(III) oxide |
Nature:
1. It is a white crystalline solid and belongs to inorganic compounds.
2. Soluble in water and relatively stable in air.
3. It has a certain degree of corrosiveness and should be avoided from contact with skin and eyes.
Usage:
1. It is widely used in the field of optics for preparing laser materials and enhancing fluorescence performance.
2. Used in biomedical research, such as analysis and diagnosis, as a catalyst in catalytic reactions, and in the field of materials science.
Method:
It can be prepared by dissolving erbium oxide in nitric acid.
1. Dissolve erbium nitrate in an appropriate amount of water, and then crystallize to obtain a white crystalline solid of erbium nitrate.
2. Dry the solid to obtain the product of erbium nitrate.
Security information:
1. It is a corrosive compound that should be avoided from direct contact with the skin and eyes. Protective gloves and goggles should be worn during operation.
2. When handling erbium nitrate, it should be operated in a well ventilated area to avoid inhaling its vapor.
3. It should be kept away from fire sources and oxidants, stored in a dry and ventilated place, and avoid mixing with other chemicals.
4. If accidentally touching the skin or eyes, immediately rinse with plenty of water and seek medical help.
1. Heat erbium oxide to a high temperature and dissolve it in nitric acid, and then evaporate and concentrate to obtain its pentahydrate or hexahydrate salt.
2. Under heating, the excess erbium carbonate reacts with concentrated nitric acid, and after the reaction, the unreacted oxide is filtered and separated. Cooling the obtained nitrate solution to obtain erbium (III) carbonate pentahydrate.
3. Dissolve erbium carbonate in slightly excess 8mol/L nitric acid, evaporate and concentrate to paste, and recrystallize with dilute nitric acid for the second time. Then put it in a 50% ~ 60% sulfuric acid dryer for drying.
Used as an analytical reagent, it can also be used to prepare inorganic nanomaterials. Examples of applications are as follows:
1. A preparation method of erbium nitrate doped zinc oxide nanofibers, comprising:
1) Ultrasonic degreasing the matrix in acetone, anhydrous ethanol and deionized water for 20 minutes;
2) PVA, zinc acetate, glacial acetic acid and erbium nitrate are mixed and stirred at 60 ℃ for 3 hours to obtain spinning solution. The mass ratio of PVA, zinc acetate and glacial acetic acid is 1:2:4.1; The content of erbium nitrate is 0.45%.
3) The spinning solution is collected on the substrate by electrospinning; the electrospinning voltage is 18KV, and the distance between the syringe and the substrate is controlled at 17cm. The matrix is aluminum foil.
4) The collected fibers are calcined in an oxygen atmosphere, and the temperature is raised to a calcination temperature of 600°C at a heating rate of 3°C/min. Calcination time is 1 hour.
2. A method for preparing erbium-doped tetragonal perovskite structure lead titanate single crystal nanofibers, comprising the following steps:
1) Add erbium nitrate to ethylene glycol methyl ether, stir evenly, prepare erbium glycol methyl ether solution with a mass concentration of 5%, add tetrabutyl titanate to ethylene glycol methyl ether, stir evenly, prepare tetrabutyl titanate ethylene glycol methyl ether solution with a concentration of 0.5M/L;
2) According to the chemical formula PbErxTi1-xO3 of the erbium-doped tetragonal perovskite structure lead titanate single crystal nanofiber to be prepared, 0.005 ≤ X≤ 0.04, add erbium glycol methyl ether solution to tetrabutyl titanate-ethylene glycol methyl ether solution, and stir and mix evenly;
3) Drop the ammonia solution with a mass concentration of 30% to step 2) The mixed erbium nitrate-tetrabutyl titanate-ethylene glycol methyl ether co-solution, and stir to hydrolyze erbium nitrate and butyl titanate to generate a white precipitate. After filtration and washing, erbium-titanium hydroxide co-precipitation is obtained;